Explode! Sage Mode

is episode 163 of the Naruto Shippūden anime.

Synopsis
Naruto is summoned by Shima along with some other toads, visibly surprised to see Konohagakure utterly destroyed. Knowing full well that Pain is responsible, Naruto confonts him. However before they could do battle Tsunade appears to apprehend Pain. Despite her determination she was helpless since she had used her most powerful jutsu (Souzou Saisei) to heal and protect the villagers from Pain's Shinra Tensei. Naruto quickly destroys the rejuvenated Asura Path after it tries to assault Tsunade. Naruto then ordered Gamakichi to take Tsunade to a safe place and to inform everyone not to interfere in his battle with Pain. The Deva Path stood by while the Animal Path sent out its summons against Naruto. Using Sage Art: Big Ball Rasengan, Naruto sent the summons flying into the air to be dispatched by Gamabunta, Gamaken and Gamahiro. He proceeded to disable the Preta Path and prepare Wind Release: Rasenshuriken. Deva Path claimed that Naruto and he had the same teacher and should have the same visions on peace, involving Naruto sacrificing his life and handing over the tailed beast for that cause. Naruto angrily rejected this view and threw the new Rasenshuriken, in the process shocking Fukasaku, Shima, Sakura, and Kō Hyūga.