The Light and Dark of the Mangekyō Sharingan

is episode 136 of the Naruto: Shippūden anime.

Synopsis
As Zetsu watches on, Itachi explains to Sasuke the secret behind the Mangekyō Sharingan, and the history of the Uchiha clan. Besides being able to tame the Nine-Tailed Fox, the Mangekyō will eventually rob the user of their eyesight and the only way to overcome this obstacle is to steal the Sharingan of that person's sibling. Sasuke retaliates against Itachi's assaults, but he is eventually pinned to a wall and has one of his eyes seemingly stolen by Itachi.